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应用生态学报 ›› 2010, Vol. 21 ›› Issue (07): 1892-1898.

• 综合评述 • 上一篇    

核磁共振技术在沉积物磷素组分及迁移转化规律研究中的应用

钱轶超,陈英旭**,楼莉萍,崔昕意,罗 玲   

  1. 浙江大学环境保护研究所, 杭州 310029
  • 出版日期:2010-07-20 发布日期:2010-07-20

Application of 31P nuclear magnetic resonance technology in the study of phosphorus fractions and their translocation and transformation in sediments: A review.

QIAN Yi-chao, CHEN Ying-xu, LOU Li-ping, CUI Xin-yi, LUO Ling   

  1. Institute of Environmental Science and Technology, Zhejiang University, Hangzhou 310029, China
  • Online:2010-07-20 Published:2010-07-20

摘要: 沉积物磷素释放是造成湖泊水体发生富营养化的主要原因之一,而磷的活性又取决于其在沉积物中的化学赋存形态.磷-31核磁共振(31P NMR)技术因可以增强研究者对环境中磷素组分信息的认识而广受关注.本文主要综述了该技术在沉积物磷素形态表征以及迁移转化规律方面的研究成果,对技术原理和分类、分析流程以及具体应用领域进行了全面阐述.目前,应用核磁共振技术分析沉积物磷素的研究主要集中于不同形态磷化合物表征、微生物对磷素迁移转化的影响和定量研究三方面,而关于提取剂和提取方法的研究也是热点之一.最后,对未来31P NMR技术在环境样品中应用研究的重点和发展趋势进行了展望.

关键词: 核磁共振, 沉积物, 磷组分, 迁移转化, 提取, 水生生物, 氧化胁迫, 六价铬, 抗氧化系统

Abstract: Phosphorus (P) release from sediments is one of the most important causes of lake eutrophication, while the activity of P is determined by P chemical
form. Due to its advantages in improving our knowledge about the P fractions in environmental samples, the 31P nuclear magnetic resonance (31P NMR) technology has received extensive attention. This paper summarized the current studies on the characterization, translocation, and transformation of P fractions in sediments by using this technology, and described the technical principles, classification, analytical procedures, and specific application fields of this technology. At present, the researches of sediment P by using 31P NMR technology were focused on the characterization of different P forms, the effects of microbes on the P translocation and transformation, and the quantitative analysis of different P fractions. The studies on the P-extracting agents and extraction methods were the hot topics as well. The potential issues and research trends about the application of 31P NMR technology in environmental samples were also discussed.

Key words: nuclear magnetic resonance, sediment, phosphorus fraction, translocation and transformation, extraction, aquatic organism, oxidative stress, hexavalent chromium, antioxidant system.