欢迎访问《应用生态学报》官方网站,今天是 分享到:

应用生态学报 ›› 2010, Vol. 21 ›› Issue (12): 3212-3216.

• 研究报告 • 上一篇    下一篇

好气条件下不同形态外源砷在土壤中的转化

和秋红,曾希柏**,李莲芳,白玲玉   

  1. 中国农业科学院农业环境与可持续发展研究所/农业部农业环境与气候变化重点开放实验室,北京 100081
  • 出版日期:2010-12-18 发布日期:2010-12-18

Transformation of different exogenous arsenic forms in soil under aerobic condition.

HE Qiu-hong, ZENG Xi-bai, LI Lian-fang, BAI Ling-yu   

  1. Ministry of Agriculture Key Laboratory of Agro-Environment &Climate Change, Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences, Beijing 100081, China
  • Online:2010-12-18 Published:2010-12-18

摘要: 在35%的田间持水量下,通过模拟试验研究了外源二甲基砷酸盐(DMA)、一甲基砷酸盐(MMA)、五价无机砷[As(V)]在土壤中的形态转化.结果表明: 外源砷进入土壤后,其含量均有随时间推延而逐渐下降的趋势,两种不同形态的有机砷DMA和MMA在土壤中主要发生脱甲基化过程,经150 d的恒温恒湿培养,其在土壤中主要转化为As(V),DMA处理仅在120 d时检测到少量MMA,而MMA处理则在7~60 d内均有少量的DMA生成.培养结束时土壤中DMA和MMA含量均显著降低(P<0.01),降幅分别为99.5%、94.3%,而两者的主要转化产物As(V)的含量则分别显著增加了4.61和5.15倍.表明外源有机态砷在土壤中基本上被转化为无机形态;与有机态外源砷相比,外源As(V)进入土壤后其形态基本上没有发生转化.

关键词: 好气条件, 土壤, 砷形态, 转化, 棘头梅童鱼, 长江口, 食物组成, 摄食习性, 季节变化

Abstract: An incubation test was conducted to study the transformation of exogenous dimethylarsenic acid (DMA), monomethylarsenic acid (MMA), and arsenate [As(V)] in soil under the condition of 35% of  water-holding capacity. After added into soil, the concentrations of test arsenic forms all showed a decreasing trend with time. The DMA and MMA were mainly demethylated, and after 120 days incubation at constant temperature and humidity, transformed into As(V). A small amount of MMA was detected in the treatment with added DMA on the 120th day of incubation, and a small amount of DMA was detected in the treatment with added MMA during the period of 7-60 days incubation. By the end of the incubation test, the concentrations of added DMA and MMA in soil decreased significantly (P<0.01), with the decrement being 99.5% and 94.3% and the concentration of transformed As(V) increased by 4.61 and 5.15 times, respectively. Comparing with DMA and MMA, the As(V) after added into soil had less form transformation.

Key words: aerobic condition, soil, arsenic form, transformation, Collichthy lucidus, the Yangtze Estuary, diet composition, feeding habit, seasonal variation.