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应用生态学报 ›› 2017, Vol. 28 ›› Issue (9): 3087-3098.doi: 10.13287/j.1001-9332.201709.009

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固体介质中的重金属源解析及其在中国近海沉积物中的应用

梁宪萌1,2, 宋金明1,2,3*, 袁华茂1,2,3, 李学刚1,2,3, 李宁1,2,3, 段丽琴1,2,3   

  1. 1中国科学院海洋生态与环境科学重点实验室中国科学院海洋研究所, 山东青岛 266071
    2中国科学院大学, 北京 100039
    3青岛海洋国家实验室海洋生态与环境功能实验室, 山东青岛 266237
  • 收稿日期:2016-12-29 出版日期:2017-09-18 发布日期:2017-09-18
  • 通讯作者: * E-mail: jmsong@qdio.ac.cn
  • 作者简介:梁宪萌, 女, 1990年生, 博士研究生. 主要从事海洋环境生物地球化学循环研究. E-mail: lxm19900625@163.com
  • 基金资助:

    本文由国家重点基础研究发展计划(973)项目(2015CB452901,2015CB452902 )、国家自然科学基金委-山东省联合资助项目(U1606404)、青岛海洋国家实验室“鳌山人才”专项(2015ASTP-OS13)和国家自然科学基金项目(41676068)资助

Source apportionment of heavy metals in solid and its application in coastal sediment of China.

LIANG Xian-meng1,2, SONG Jin-ming1,2,3, YUAN Hua-mao1,2,3, LI Xue-gang1,2,3, LI Ning1,2,3, DUAN Li-qin1,2,3   

  1. 1CAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, Shandong, China;
    2University of Chinese Academy of Sciences, Beijing 100049, China;
    3Function Laboratory of Marine Ecolo-gy and Environmental Sciences, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266237, Shandong, China.
  • Received:2016-12-29 Online:2017-09-18 Published:2017-09-18
  • Contact: * E-mail: jmsong@qdio.ac.cn
  • Supported by:

    This work was supported by the National Program on Key Basic Research Project of China (973 Program) (2015CB452901, 2015CB452902), the Joint Fund of National Natural Science Foundation and Shandong Province for Marine Science Research Centers (U1606404), Aoshan Talents Program supported by Qingdao National Laboratory for Marine Science and Technology (2015ASTP-OS13), and National Natural Science Foundation of China (41676068).

摘要: 沉积物中重金属源解析对甄别人为活动与自然变化对近海生态系统演化的影响有重要作用.本文总结了近年来污染物源解析常用的多元统计分析、地球化学方法和地质统计分析3种主要研究方法,剖析了不同方法的优劣及适用性,提出正定矩阵因子分析、Pb同位素示踪在重金属来源定量化研究中具有良好应用前景.梳理了中国近海沉积物中重金属来源的主要研究结果,发现河口和海湾是沉积物重金属受人为来源影响剧烈的典型近海区域,不同定量解析方法(多元统计分析、背景值估算、Pb同位素分析)均表明中国近海沉积物重金属的人为来源贡献率接近或超过50%.当前中国近海沉积物中重金属源解析研究还存在源识别端元模糊、解析结果缺乏相应的可靠性评价等问题.据此提出近海沉积物重金属源解析研究应使用多种解析技术手段综合、集成与优化,提高源解析的准确性;建立完善指标体系,筛选代表特定人为活动和自然过程的指标;甄别人为源重金属入海方式及过程,为沉积物数据信息的解译提供理论基础.

Abstract: Source apportionment of heavy metals in sediments is significant to distinguish the influence of human activities from nature changes on offshore eco-environment evolution. This overview focused on three widely used source apportionment methods: Multivariate statistical technique, geochemical method and geostatistical analysis and highlighted that the positive matrix factorization and lead isotopic trace were two relatively preferable methods to quantitatively assess the anthropogenic source of heavy metals. Based on the heavy metal concentrations in coastal sediments of China, heavy metals were primarily of anthropogenic origin with their contribution close to or higher than 50% in coastal sediment of China evaluated by combination of different source identification me-thods (multivariate analysis, estimation based on background value and lead isotopic trace), and estuaries and bays were typical polluted regions. The current researches on source apportionment had the problems that the source endmembers were still vague and the interpretation of data lacks corresponding reliability evaluation. The future research should be focused on the integration and optimization of multi-methods to improve the accuracy of source apportionment, extracting informative indicators to represent specific anthropogenic activities or natural source and recognizing the geoche-mical process and mechanism of anthropogenic emissions of heavy metals when entering into coastal environment to provide referential fingerprints for source interpretation.