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生态学杂志 ›› 2011, Vol. 30 ›› Issue (05): 933-938.

• 汞的生物地球化学专辑 • 上一篇    下一篇

贵阳市大气降水中汞的分布特征

刘娜1,仇广乐1**,冯新斌1,LANDIS Matthew2,付学吾1,商立海1   

  1. 1中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550002| 2Office of Research and Development, USEPA, Research Triangle Park, NC 27709, USA
  • 出版日期:2011-05-08 发布日期:2011-05-08

Distribution characteristics of mercury in precipitation of Guiyang, China.

LIU Na1, QIU Guang-le1**, FENG Xin-bin1, LANDIS Matthew3, FU Xue-wu1, SHANG Li-hai1   

  1. 1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China|2Office of Research and Development, USEPA, Research Triangle Park, NC 27709, USA
  • Online:2011-05-08 Published:2011-05-08

摘要: 于2008年7—9月对贵阳市中心城区采集的21个大气降水进行了总汞、甲基汞及阴、阳离子浓度的测定,分析了大气降水中总汞与阴阳离子间的相互关系。结果表明:大气降水中总汞的平均含量为18 ng·L-1,变化范围为0.4~57.4 ng·L-1;甲基汞的平均含量为0.07 ng·L-1,变化范围为0.02~0.2 ng·L-1。大气降水中的阴离子以SO2-4和NO-3为主,其浓度平均值分别为151和145 mol·L-1;阳离子主要以Ca2+为主,平均浓度达到了123 mol·L-1,变化范围为3.7~560 mol·L-1,其次是NH4+和Mg2+,其浓度平均值分别为52.2和20.4 mol·L-1。通过分析降水中总汞和阴阳离子之间的相互关系,发现总汞和阴离子SO2-4具有显著的相关性,与F-有一定的相关性,而与NO-3不具有相关性。由此初步判定,大气降水中的总汞主要来源于燃煤等人为释放源。

关键词: 栉孔扇贝, 生物沉积法, 滤水率, 吸收率, 元素收支

Abstract: A study of the daily event precipitation in Guiyang was taken between July and September, 2008. The average concentration of total Hg (THg) in daily event precipitation was 18 ng·L-1 with a range from 0.4 to 57.4 ng·L-1; the average concentration of methyl Hg (MeHg) in daily event precipitation was 0.07 ng·L-1, with a range from 0.02 to 0.2 ng·L-1. The main inorganic ions were SO2-4, NO-3, Ca2+, NH4+, and Mg2+. The average concentrations of SO2-4 and NO-3 were 151 mol·L-1 and 145 mol·L-1, respectively. The average concentration of Ca2+ was 123 mol·L-1 with a range from 3.7 mol·L-1 to 560 mol·L-1. The average concentrations of NH4+ and Mg2+ were 52.2 mol·L-1 and 20.4 mol·L-1, respectively. According to the relationships between the concentrations of THg and inorganic ions, we identified that the possible sources were fossil fuels burning.

Key words: Chlamys farreri, Biodeposition method, Clearance rate, Absorption efficiency, Element budget