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紫色土有机质对团聚体吸附-解吸Pb2+的影响

李璐娟,夏建国**,刘朗   

  1. (四川农业大学资源环境学院, 成都 611130)
  • 出版日期:2014-05-10 发布日期:2014-05-10

Effect of purple soil organic matter on adsorption and desorption of Pb2+ by aggregates.

LI Lu-juan, XIA Jian-guo**, LIU Lang   

  1. (College of Resources and Environment, Sichuan Agricultural University, Chendu 611130, China)
  • Online:2014-05-10 Published:2014-05-10

摘要:

选取名山河流域4种土地利用方式(茶园、旱地、水田、林地)的紫色土为对象,采用平衡液吸附法及NH4OAc、EDTA解吸法研究有机质对Pb2+在全土及各粒径团聚体中吸附解吸的影响,用Langmuir、Freundlich和Temkin方程对等温吸附过程进行拟合。结果表明:去除有机质前后,4种土地利用方式紫色土全土及各粒径团聚体对Pb2+的吸附量均随Pb2+初始浓度的增大而增加,各粒径团聚体对Pb2+的吸附量排序为(<0.002 mm)>2~0.25 mm>全土>0.053~0.002 mm>0.25~0.053 mm,Freundlich方程拟合效果最佳,分布系数Kd值与Pd2+初始浓度呈曲线负相关,林地对Pb2+的吸附容量最大,茶园最小;4种土地利用方式紫色土全土及各粒径团聚体以静电吸附方式为主,络合吸附方式为辅,非解吸率大小关系均为林地>旱地>水田>茶园,说明茶园紫色土对Pb2+的固持能力最弱,林地最强。去除有机质后,4种土地利用方式紫色土全土及各粒径团聚体对Pb2+的吸附量均有所降低,相较于茶园和水田,林地和旱地吸附减少量更为明显,Pd2+最大吸附减少量与有机质去除量呈极显著正相关,4种土地利用方式紫色土NH4OAc解吸率明显增加,EDTA解吸率相应减少,非解吸率均有不同程度的降低。
 

关键词: 大管鞭虾, 食性变化, 摄食强度, 营养级, 饵料组成

Abstract: The purple soils collected from four land-use types, including tea garden, dry land, paddy field and woodland in the Mingshan River watershed, were used to investigate the effect of purple soil aggregate components on the adsorption and desorption of Pd2+ by aggregates using the isothermal adsorption method of equilibrium and the desorption method of NH4OAc and EDTA. The results showed that before and after removing organic matter, the absorbance of Pd2+ by differently sized aggregates increased with the initial Pd2+ concentration, in a sequence of (<0.002 mm) > 2-0.25 mm > bulk soil > 0.053-0.002 mm > 0.25-0.053 mm. The Freundlich equation was the best to fit the adsorption pattern. The distribution coefficient Kd was negatively correlated with the initial Pb2+ concentration. Woodland soil showed the maximum capacity of Pb2+ adsorption while tea garden soil showed the minimum. The adsorption was mainly based on electrostatic adsorption, supplemented by complexation adsorption. The nondesorption rate was in order of woodland > dry land > paddy field > tea garden, indicating that the holding capacity of the tea garden soil was the weakest and woodland soil was the strongest. After removing the organic matter, the Pd2+ absorbance by differently sized aggregates all decreased. The adsorption reductions of woodland and dry land soils were more obvious compared with those of tea garden and paddy soils. The reduction of maximum adsorption had a significant positive correlation with the amount of organic matter removal. In purple soils of the four landuse types, NH4OAc desorption rate increased obviously while EDTA desorption rate decreased accordingly, and the nondesorption rate decreased in varying degrees.

Key words: diet composition, feeding change, trophic level, feeding intensity, Solenocera melantho