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Variation characteristics of water-soluble inorganic ions in size-segregated atmospheric particles in Chengdu in winter.

YANG Zhou1,2, LI Xiao-dong1**, YU Jing3, SHI You-xiang3, DU Feng3   

  1. (1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China; 2 University of Chinese Academy of Sciences, Beijing 100049, China; 3College of Environment and Civil Engineering, Chengdu University of Technology, Chengdu 610059, China)
  • Online:2013-03-10 Published:2013-03-10

Abstract: By means of the Andersen stage sampler, size-segregated atmospheric particles were collected in Chengdu City in winter, 2010. The size distribution spectra of major water-soluble inorganic ions (SO42-, NO3-, Cl-, F-, NH4+, Ca2+, Mg2+, K+, and Na+) were determined. Mass contents of SO42-, NO3-, NH4+, Cl-, K+ and Na+ mainly concentrated in the fine particles within the size range of 3.3-0.65 μm, and those of Ca2+ and Mg2+ concentrated in the coarse particles (11.0-4.7 μm). SO42-, NO3-, NH4+ and Ca2+ were the major inorganic ions in the collected atmospheric particles. Under different weather conditions, mass concentrations of SO42- and NO3- decreased in sequence of foggy day, cloudy day and rainy day, and their contents in the foggy day were about 2.5 and 5 times higher than that in cloudy day and rainy day, respectively. Accordingly, the other ions were also about 2 times higher. In the all sizesegregated particles, the ratios of \[NO3-\]/\[SO42-\] were less than 1.0, indicating that the air pollution in  Chengdu City are still dominated by stationary source (coal combustion) while the mobile pollution source (main as vehicle exhaust) is becoming increasingly important.

Key words: Quercus wutaishanica population, age structure, life table, survival curve.