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Distribution, sources and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge from Guiyang City.

YANG Shao-bo1, LI Jiang1,2**, ZHANG Chun-hui1, WU Yong-gui1,2, YAN Chang-lun1   

  1. (1College of Resources and Environmental Engineering, Guizhou University, Guiyang 550025, China; 2Institute of Applied Ecology, Guizhou University, Guiyang 550025, China)
  • Online:2015-06-10 Published:2015-06-10

Abstract: Sixteen US EPA priority polycyclic aromatic hydrocarbons (PAHs) in sewage sludge from 5 wastewater treatment plants in Guiyang City, Southwest China, were analyzed using Soxhletextraction and GCMS method. Possible sources were identified using the diagnostic ratios of PAHs and potential risks were assessed based on the toxic equivalent concentration of BaP (TEQBaP). The results showed that total PAHs concentrations in the samples were in the range of 1.90-4.27 mg·kg-1, which was lower than those of the most of well developed countries and areas. PAHs in the sewage sludge were dominated by 2-4 rings PAHs and mainly stemmed from biomass burning and domestic coal combustion, with some characteristics of vehicle emission. The risk assessment showed that the toxicity equivalent concentration of PAHs (TEQBaP16) was in the range of 0.09-0.29 mg·kg-1, in which 97% of the total TEQBaP originated from 7 carcinogenic PAHs. The TEQBaP10 was 0.07-0.24 mg·kg-1, indicating higher carcinogenicity and ecological risk.

Key words: dark loessial soil, water use efficiency., tillage pattern, organic carbon, soil aggregate