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The cycle and coupling effect of carbon and sulfur in cascade reservoirs: A case study of Jialing River.

YANG Meng-di1, CUI Gao-yang2,3, LI Qin-kai1, HUANG Jun2,3, LI Si-qi1, ZHANG Jun1, TAO Yue-le1, LI Xiao-dong1*   

  1. (1 Institute of SurfaceEarth System Science, Tianjin University, Tianjin 300072, China; 2State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China; 3University of Chinese Academy of Sciences, Beijing 100049, China)
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  • Online:2018-03-10 Published:2018-03-10

Abstract: Damming on the rivers has important effects on biogeochemical cycles of carbon,nitrogen and sulfur. To clarify the responses of C and S elements under the influence of cascade reservoirs, four representative cascade reservoirs in Jialing River were selected as the research objects. Samples of inflow, outflow, and stratified water in four cascade reservoirs were collected in winter (January) and summer (July) of 2016. Dissolved inorganic carbon (DIC) concentration, SO42- concentration and isotopic compositions of δ13CDIC and δ34S were analyzed. The results showed that: (1) Water chemistry was mainly controlled by carbonic acid balance. At the same time, H2SO4, derived from pyrite and atmospheric SO2 oxidation, was widely involved in regional carbonate weathering; (2) DIC was mainly affected by soil CO2 and carbonate. SO42- was mainly controlled by precipitation and pyrite oxidation process; (3) Significant correlations (P<0.05) existed among paired characters of reservoir water DIC concentration, SO42- concentration, δ34S value and δ13CDIC value, indicating that the spatial and temporal dynamics of C and S elements in reservoir were affected by similar processes (physical, chemical, and biological). After intercepting of the dam, the river water environment and nutrient cycle had undergone great changes. The use of C and S double isotopes can effectively track the limnetic evolution of reservoirs.

Key words: pollution degree, leaf surface morphology, PM25 adsorption amount, water-soluble ionic characteristics