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植物叶片吸滞PM2.5等大气颗粒物定量研究方法初探——以毛白杨为例

张志丹1,席本野1,曹治国2,贾黎明1**   

  1. (1北京林业大学省部共建森林培育学科与保护重点实验室, 北京 100083; 2清华大学环境学院环境模拟与污染控制国家重点联合实验室/持久性有机污染物研究中心, 北京 100084)
  • 出版日期:2014-08-18 发布日期:2014-08-18

Exploration of a quantitative methodology to characterize the retention of PM2.5 and other atmospheric particulate matter by plant leaves: Taking Populus tomentosa  as an example.

ZHANG Zhi-dan1, XI Ben-ye1, CAO Zhi-guo2, JIA Li-ming1   

  1. (1Ministry of Education Key Laboratory for Silviculture and Conservation, Beijing Forestry University, Beijing 100083, China; 2State Key Joint Laboratory of Environment Simulation and Pollution Control/POPs Research Center, School of Environment, Tsinghua University, Beijing 100084, China)
  • Online:2014-08-18 Published:2014-08-18

摘要: 以毛白杨为例,提出一种利用激光粒度仪和天平定量评估植物叶片吸滞细颗粒物(PM2.5,直径d≤2.5 μm)等大气颗粒物能力的方法——洗脱称量粒度分析法(EWPA),实现了对植物叶片吸滞大气颗粒物质量和粒径分布的直接、准确测定,可操作性强.首先,进行预试验对试验方法的稳定性进行检验;其次,通过对叶片进行清洗、离心洗液、烘干等步骤收集其吸滞的颗粒物,然后对颗粒物称量,并采用激光粒度仪测定颗粒物的粒径分布;最后,利用叶面积和林分叶面积指数数据换算得到单位面积叶片和林分的各径级颗粒物吸滞量.在北京市奥林匹克森林公园内一片毛白杨林分(27 d未经历降雨)中应用该法,测得毛白杨叶片吸滞大气颗粒物的粒径均值为17.8 μm,吸滞PM2.5、可吸入颗粒物(PM10,d≤10 μm)和总悬浮颗粒物(TSP,d≤100 μm)的体积百分比分别为13.7%、47.2%和99.9%;叶片的PM2.5、PM10、TSP和总颗粒物吸滞量分别为8.88×10-6、30.6×10-6、64.7×10-6和64.8×10-6 g·cm-2;林分的PM2.5、PM10、TSP和总颗粒物吸滞量分别为0.963、3.32、7.01和7.02 kg·hm-2.

Abstract: Taking Populus tomentosa as an example, a methodology called elutionweighingparticle sizeanalysis (EWPA) was proposed to evaluate quantitatively the ability of retaining fine particulate matter (PM2.5, diameter d≤2.5 μm) and atmospheric particulate matter by plant leaves using laser particle size analyzer and balance. This method achieved a direct, accurate measurement with superior operability about the quality and particle size distribution of atmospheric particulate matter retained by plant leaves. First, a preexperiment was taken to test the stability of the method. After cleaning, centrifugation and drying, the particulate matter was collected and weighed,  and then its particle size distribution was analyzed by laser particle size analyzer. Finally, the mass of particulate matter retained by unit area of leaf and stand was translated from the leaf area and leaf area index. This method was applied to a P. tomentosa stand which had not experienced rain for 27 days in Beijing Olympic Forest Park. The results showed that the average particle size of the atmospheric particulate matter retained by P. tomentosa was 17.8 μm, and the volume percentages of the retained PM2.5, inhalable particulate matter (PM10 , d≤10 μm) and total suspended particle (TSP, d≤100 μm) were 13.7%, 47.2%, and 99.9%, respectively. The masses of PM2.5, PM10, TSP and total particulate matter were 8.88×10-6, 30.6×10-6, 64.7×10-6 and 64.8×10-6g·cm-2, respectively. The retention quantities of PM2.5, PM10, TSP and total particulate matter by the P. tomentosa stand were 0.963, 3.32, 7.01 and 7.02 kg·hm-2, respectively.