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Photochemical degradation of chlorpyrifos in water

WU Xiangwei1; HUA Rimao1; TANG Feng1; LI Xuede1; CAO Haiqun1; YUE Yongde2   

  1. 1Key Laboratory of Anhui AgroFood Safety, College of Resources and Environment, Anhui Agricultural University, Hefei 230036, China; 2International Center for Bamboo & Rattan, Beijing 100102, China
  • Received:2005-07-18 Revised:2006-04-24 Online:2006-07-18 Published:2006-07-18

Abstract: In this paper, the effects of different light sources, temperature, pH, and water quality on the photochemical degradation of chlorpyrifos in water were examined under natural and simulated solar irradiation. The results showed that the photochemical degradation of chlorpyrifos in water followed the first order reaction, and its half-life was 0.62, 6.92, 19.74 and 22.50 h under high pressure mercury lamp (HPML), xenon lamp (XL), ultraviolet lamp (UV), and sunlight (SL) irradiation, respectively. Temperature had a significant effect on the degradation rate of chlorpyrifos, which was increased with increasing temperature and reached the maximum at 35 ℃. The degradation rate of chlorpyrifos was stable both in acid and in neutral buffer solution, but enhanced in alkaline buffer solution. Water quality also had a significant effect, with a decreasing degradation rate of chlorpyrifos in the sequence of distilled water>tap water>river water>lake wate>paddy water.

Key words: Landscape indices, Landscape pattern, Landscape ecology