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应用生态学报 ›› 2010, Vol. 21 ›› Issue (07): 1835-1843.

• 研究报告 • 上一篇    下一篇

某农药工业园区周边土壤重金属含量与风险评价

石宁宁,丁艳锋,赵秀峰,王强盛**   

  1. 南京农业大学农业部南方作物生理生态重点开放实验室,南京 210095
  • 出版日期:2010-07-20 发布日期:2010-07-20

Heavy metals content and pollution risk assessment of cropland soils around a pesticide industrial park.

SHI Ning-ning, DING Yan-feng, ZHAO Xiu-feng, WANG Qiang-sheng   

  1. Ministry of Agriculture Key Laboratory of Crop Physiology &Ecology in Southern China, Nanjing Agricultural University, Nanjing 210095, China
  • Online:2010-07-20 Published:2010-07-20

摘要: 以苏南某农药工业园区周边30 km2区域为研究区,采用同心圆法采集土壤样品183个,分析了农药工业园区周边土壤Cd、Cr、Cu、Ni、Pb、Zn、Hg和As 8种重金属含量、空间变异性、来源及潜在风险.结果表明:以自然背景值为评价标准,研究区表层土壤Hg、Cu、Cd和Pb平均含量超过自然背景值,其中Hg和Cu含量最高;以国标二级标准为评价标准,土壤Cd、Cr、Ni、Pb、Zn、As 6种重金属的单项污染指数平均值均小于1,Hg和Cu分别为1.59和1.05.在农药工业园区周边土壤重金属污染较重的东南方向和西北方向,随着与园区距离的增加,土壤Cd、Ni、Pb、Cr、As、Hg、Zn和Cu含量先上升、后下降、再趋于平稳.通过分析农药工业园区周边土壤重金属综合污染指数发现,距离园区约200~1000 m周边土壤污染的风险较大,而1000 m以外逐渐达到安全范围.利用地统计学和GIS相结合进行分析发现,8种重金属污染指数有明显的空间变异.依据相关分析与主成分分析结果推测,Zn、Ni、Cr、Pb和As主要来源于成土母质,而Hg、Cu和Cd主要与人类活动有关.

关键词: 农药工业园区, 土壤重金属, 风险评价, 重点生态功能区, 水源涵养, 水土保持, 防风固沙, 生物多样性维护

Abstract: By the method of concentric circle distribution method, a total of 183 topsoil samples were collected from 30km2 area around a pesticide industrial park in south Jiangsu Province, with the content and pollution index of soil Cd, Cr, Cu, Ni, Pb, Zn, Hg and As analyzed. The average contents of Hg, Cu, Cd,and Pb in the top soils were higher than those of the natural background values, and the contents of Hg and Cu were the highest. Taking the national standard II as the assessment criterion, the average pollution index values of Cd, Cr, Cu, Ni, Pb, Zn, and As in the top soils were all below 1, while those of the Hg and Cu were 1.59 and 1.05, respectively. In the southeast and northwest to the pesticide industrial park, soil heavy metals contamination was more serious, and, with the increasing distance to the park, the contents of soil Cd, Ni, Pb, Cr, As, Hg, Zn, and Cu increased first and then decreased to a stable level. The comprehensive pollution index of test metals indicated that the areas 200-1000 meter around the industrial park were of high risk in soil heavy metals contamination, while the areas 1000 meter beyond were safety. By using geostatistics and GIS, it was found that the pollution index of the eight heavy metals had significant spatial variability. Based on the principal component analysis and correlation analysis, it was speculated that the Zn, Ni, Cr, Pb, and As were mainly from soil parent materials, while the Hg, Cu, and Cd were mainly related to human activities.

Key words: pesticide industrial park, soil heavy metal, risk assessment, key ecological function zones, water conservation, soil conservation, wind prevention and sand fixation, biodiversity maintenance.