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几种物质对苯噻草胺在水中光降解的影响

褚明杰1;岳永德2,3;花日茂3;汤锋3   

  1. 1安徽农业大学理学院,合肥 230036;2国际竹藤网络中心,北京 100102;3安徽省农产品安全重点实验室,合肥 230036
  • 收稿日期:2005-04-04 修回日期:2005-08-22 出版日期:2006-01-18 发布日期:2006-01-18

Effects of dissolved compounds on photodegradation of mefenacet in water

CHU Mingjie1;YUE Yongde2,3;HUA Rimao3;TANG Feng3   

  1. 1College of Science,Anhui Agricultural University,Hefei 230036,China;2International Center For Bamboo and Rattan,Beijing 100102,China;3Key Laboratory of AgriFood Safety of Anhui Province,Hefei 230036,China

  • Received:2005-04-04 Revised:2005-08-22 Online:2006-01-18 Published:2006-01-18

摘要: 高压汞灯下不同物质对水中的苯噻草胺光化学降解的影响研究表明,NO2-和NO3-对苯噻草胺的光解有猝灭作用,其中NO3-在10∶1的添加浓度(质量浓度)下猝灭作用最明显,照光15 min猝灭率达53.3%;卤素离子对苯噻草胺光解有重原子猝灭效应,作用最强的是添加10∶1的I-(质量浓度),照光15 min 猝灭率达76.9%;4种表面活性剂随添加浓度的增大对苯噻草胺光解的阻滞作用增强,除农乳404在较低添加浓度下(质量浓度比1∶5和1∶1)对苯噻草胺的光解表现出微弱的敏化效应外,其余均表现为猝灭作用;4种除草剂(杀草丹、苄嘧磺隆、甲草胺和绿磺隆)中,只有苄嘧磺隆在低添加浓度(质量浓度比1∶10)时对苯噻草胺有光敏化作用,照光25 min光敏率为18.2%,其余除草剂各添加浓度下均对苯噻草胺表现出光猝灭作用;充氮气10 min,苯噻草胺的光解半衰期由不充氮气的7.14 min缩短为6.70 min.

关键词: 节肢动物群落, 功能集团, 种群动态, 垂直分布

Abstract: The study with high-pressure mercury lamp illuminating showed that after illuminated for 15 min,NO2- and NO3- quenched the photolysis of mefenacet,and NO3- with a concentration ratio 10∶1 (mass) had the most obvious effect,its quenching rate being up to 53.3%.Halogen ions inhibited the photolysis of mefenacet by “weight atom effect”.When the concentration ratio of I- was 10∶1,the quenching rate was 76.9% after illuminated for 15 min.Surfactants Nongru 500,Nongru 404,Nongru 601 and Nongru 603 had different effects on the photodegradation of mefenacet.At concentration ratios 1∶5 and 1∶1,only Nongru 404 showed a weak photosensitive effect,while in the other cases,all the four surfactants had photoquenching effects.Among the four herbicides benthiocarb,bensulfuron,alachlor and chlorsulfuron,only bensulfuron at low concentration ratio (1∶10) accelerated the photolysis of mefenacet,with a photosensitive proportion of 18.2% after illuminated for 25 min.Aerified N2 could accelerate the photolysis of mefenacet,and the half-life was shortened from 7.14 min to 6.70 min without aerifying N2.

Key words: Arthropod community, Functional group, Population dynamics, Vertical distribution