关键词: 碳库, 长期耕作, 侵蚀-沉积区, 碳积累速率, 稳定机制, Stewart物理-化学联合分组

Abstract: A cationic adsorbent with carboxyl groups derived from citric acid- esterified wheat straw (EWS) was prepared by the method of solid phase preparation, and a batch experiment was conducted to study the adsorption behaviors of Cu (II) and methylene blue (MB) in aqueous solution on the EWS under conditions of different initial pH, adsorbent dosage, adsorbate concentration, and contact time. The results showed that the maximum adsorption of Cu (II) and MB was obtained when the initial solution pH was ≥ 4.0. 96% of Cu (II) in 100 mg·L^-1 Cu solution and 99% of MB in 250 mg·L-1 dye solution could be removed by ≥2.0 g·L^-1 of EWS. The adsorption of Cu (II) and MB fitted the Langmuir sorption isothermal model. The maximum removal capacity (Q_m) of EWS was 79.37 mg·g^-1 for Cu (II) and 312.50 mg·g^-1 for MB, and the adsorption equilibrium of Cu (II) and MB was reached within 75 min and 5 h, respectively. The adsorption processes of Cu (II) and MB could be described by pseudo-first order and pseudosecond order kinetic functions, respectively.

Key words: long-term tillage, erosion-deposition area, carbon pool, stabilization mechanism, Stewart physical-chemical fractionation, carbon accumulation rate