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水溶性有机质对土壤吸附菲的影响

熊巍;凌婉婷;高彦征;李秋玲;代静玉   

  1. 南京农业大学资源与环境科学学院, 南京 210095
  • 收稿日期:2005-10-25 修回日期:2006-12-01 出版日期:2007-02-10 发布日期:2007-02-10

Effects of dissolved organic matter on phenanthrene adsorption by soil

XIONG Wei; LING Wan-ting; GAO Yan-zheng; LI Qiu-ling; DAI Jing-yu   

  1. College of Resource and Environmental Sciences, Nanjing Agricultural University, Nanjing
    210095, China
  • Received:2005-10-25 Revised:2006-12-01 Online:2007-02-10 Published:2007-02-10

摘要: 研究了来源于稻草腐熟物的外源水溶性有机质(DOM)和土壤本身固有的内源DOM对有机碳含量不同的3种土壤吸附菲的影响.结果表明,不同处理土壤对菲的吸附曲线均为线性,其吸附系数(Kd)与土壤有机碳含量(foc)正相关.去除内源DOM后,黄棕壤、红粘田和黑土吸附菲的Kd值增加了7.08%~21.4%,增加量(ΔKd)和增加幅度与foc正相关,表明土壤中存在的内源DOM抑制土壤对菲的吸附.而外源DOM对土壤吸附菲的影响与其浓度密切相关.在供试浓度范围(0~106 mg DOC·L-1)内,红粘田吸附菲的Kd值随加入外源DOM浓度的提高先增大后减小.外源DOM浓度为28 mg DOC·L-1时,红粘田吸附菲的Kd值增加了19.5%;而当外源DOM浓度≥52 mg DOC·L-1时,则明显抑制菲的吸附.内源和外源DOM对土壤吸附菲的影响,主要与DOM和菲在溶液中的结合作用、在土壤中的累积吸附效应等有关.

关键词: 云南松, 纵坑切梢小蠹, 伴生菌, 温度, 抗性

Abstract: This paper studied the effects of exotic and native dissolved organic matter (DOM) on the phenanthrene adsorption by three soils differed in soil organic carbon content (foc). The exotic DOM came from decayed rice straw, while the native DOM was extracted from the test soils. In all cases, the adsorption of phenanthrene by treated soils could be well described with linear-type mod-el, and there was a positive correlation between adsorption coefficient (Kd) and foc. Compared with the control, the Kd value of test soils after native DOM removed was increased by 7.08%—21.4%, and the increment (ΔKd) was positively correlated with foc, indicating that the presence of soil native DOM impeded the phenanthrene adsorption by soil. The effects of exotic DOM on phenan-threne adsorption had a close relation with its added concentration in soil-water system. Within the range of 0—106 mg DOC·L-1, the Kd value increased first, and then decreased with the increase of added exotic DOM concentration. Lower concentrations of added exotic DOM promoted the phe-nanthrene adsorption by soil, while higher concentrations (≥52 mg DOC·L-1) of it obviously im-peded this adsorption. These effects of exotic and native DOM on soil phenanthrene adsorption were considered to be related to the association of phenanthrene with DOM in solution, and the ‘cumulative adsorption effect’ between soil solid and aqueous phases.

Key words: Pinits yunnanenensis, Leptagraphium yunnanense, Tomicus piniperda, Temperature, Resistance